The combined gas law states that for a fixed mass of gas, the quantity PV/T stays constant, even as pressure, volume, and temperature
all change at the same time. Written as a two-point equation, that's P₁V₁/T₁ = P₂V₂/T₂: the initial state on the left, the final
state on the right. It's less a new law of its own than a merger of three others — Boyle’s
law, Charles’ law, and Gay-Lussac’s law — into a single relation that doesn't require any
one variable to be held still.
Definition
The combined gas law states that the ratio of pressure times volume to absolute
temperature is constant for a fixed amount of gas: P₁V₁/T₁ = P₂V₂/T₂,
no matter how many of the three variables change between the initial and final state.
The derivation is really just algebra on the three single-variable laws. Boyle’s law says P₁V₁ = P₂V₂ when
temperature is held constant. Charles’ law — covered on the main Charles law calculator — says V₁/T₁ = V₂/T₂ when pressure is held constant. Gay-Lussac’s law says P₁/T₁ = P₂/T₂
when volume is held constant. Each one is the combined gas law equation with one
variable frozen out; unfreeze all three and you get P₁V₁/T₁ = P₂V₂/T₂ back, which is why the combined law is the
natural tool once more than one thing is moving.
As with Charles’ and Gay-Lussac’s laws, temperature has to be on an absolute scale. A gas
at 20 °C isn't "twice as hot" as a gas at 10 °C, but a gas at 200 K genuinely does have
twice the average kinetic energy of one at 100 K — so this calculator always converts
your temperature entries to Kelvin before running the ratio, the same absolute-zero
safeguard the homepage's Charles' law calculator uses.