Charles Law Calculator

Combined Gas Law Calculator

Solve P₁V₁/T₁ = P₂V₂/T₂ instantly. Enter any five values and the calculator fills in the sixth, converting temperature to Kelvin for you.

Solved

Computed from the other five values.

Final Volume

V₂ = 3.817

V₂ = P₁V₁T₂ / (T₁P₂) = (1 atm × 1 m³ × 220 K) / (288.15 K × 0.2 atm) = 3.817 m³

What Is the Combined Gas Law?

The combined gas law states that for a fixed mass of gas, the quantity PV/T stays constant, even as pressure, volume, and temperature all change at the same time. Written as a two-point equation, that's P₁V₁/T₁ = P₂V₂/T₂: the initial state on the left, the final state on the right. It's less a new law of its own than a merger of three others — Boyle’s law, Charles’ law, and Gay-Lussac’s law — into a single relation that doesn't require any one variable to be held still.

Definition

The combined gas law states that the ratio of pressure times volume to absolute temperature is constant for a fixed amount of gas: P₁V₁/T₁ = P₂V₂/T₂, no matter how many of the three variables change between the initial and final state.

The derivation is really just algebra on the three single-variable laws. Boyle’s law says P₁V₁ = P₂V₂ when temperature is held constant. Charles’ law — covered on the main Charles law calculator — says V₁/T₁ = V₂/T₂ when pressure is held constant. Gay-Lussac’s law says P₁/T₁ = P₂/T₂ when volume is held constant. Each one is the combined gas law equation with one variable frozen out; unfreeze all three and you get P₁V₁/T₁ = P₂V₂/T₂ back, which is why the combined law is the natural tool once more than one thing is moving.

As with Charles’ and Gay-Lussac’s laws, temperature has to be on an absolute scale. A gas at 20 °C isn't "twice as hot" as a gas at 10 °C, but a gas at 200 K genuinely does have twice the average kinetic energy of one at 100 K — so this calculator always converts your temperature entries to Kelvin before running the ratio, the same absolute-zero safeguard the homepage's Charles' law calculator uses.

Combined Gas Law Formula and Symbols

Rearranged for whichever value is unknown, the six forms are: P₂ = P₁V₁T₂ / (T₁V₂), V₂ = P₁V₁T₂ / (T₁P₂), T₂ = T₁P₂V₂ / (P₁V₁), P₁ = P₂V₂T₁ / (T₂V₁), V₁ = P₂V₂T₁ / (T₂P₁), and T₁ = P₁V₁T₂ / (P₂V₂). The calculator above picks the right one automatically based on which single field you leave blank.

Pressure can be entered in kilopascals, atmospheres, millimetres of mercury, or pounds per square inch; volume in litres, millilitres, cubic metres, or cubic feet; and temperature in Kelvin, Celsius, or Fahrenheit. If your two readings arrived in different units — say one temperature in °C and the other already in K, or one volume in litres and the other in cubic feet — running them through the temperature converter or the volume converter first makes it easy to sanity-check the numbers by eye before they go into the six fields above. The calculator does the same conversion internally regardless, so it isn't strictly necessary — it's just a good habit for catching typos.

The six symbols in the combined gas law formula and their units
Symbol Meaning Unit
P₁ Initial pressure kPa, atm, mmHg, psi
V₁ Initial volume L, mL, m³, ft³
T₁ Initial temperature K, °C, °F
P₂ Final pressure kPa, atm, mmHg, psi
V₂ Final volume L, mL, m³, ft³
T₂ Final temperature K, °C, °F

Combined Gas Law Examples: Step by Step

Example 1

A Rising Weather Balloon

A weather balloon at ground level holds V₁ = 1 m³ of gas at P₁ = 1 atm and T₁ = 288.15 K (15 °C). As it rises, both pressure and temperature drop — by the time it reaches P₂ = 0.2 atm and T₂ = 220 K (about −53 °C), how large has the balloon become?

  • Apply: V₂ = P₁V₁T₂ / (T₁P₂) = (1 × 1 × 220) / (288.15 × 0.2) = 3.817 m³
  • Answer: V₂ ≈ 3.817 m³

The balloon nearly quadruples in size — the pressure drop (which alone would let it expand five-fold) is only partly offset by the temperature drop (which alone would shrink it), and the two effects net out to a factor of roughly 3.8.

Example 2

Heating a Compressed Gas Cylinder

A steel cylinder holds V₁ = 50 L of compressed gas at P₁ = 150 atm and T₁ = 293.15 K (20 °C). Left in the sun, it heats to T₂ = 323.15 K (50 °C) and the internal pressure climbs to P₂ = 180 atm. What is the effective volume V₂ of that same gas at the new pressure and temperature?

  • Apply: V₂ = P₁V₁T₂ / (T₁P₂) = (150 × 50 × 323.15) / (293.15 × 180) ≈ 45.93 L
  • Answer: V₂ ≈ 45.93 L

The rigid steel cylinder itself doesn't change volume, of course — this V₂ is the volume the same gas would occupy at 180 atm and 323.15 K if it were free to expand, which is exactly the number engineers use to check a cylinder's pressure rating against its temperature exposure.

Combined Gas Law vs the Single-Variable Laws

The combined gas law is the right tool specifically when more than one of pressure, volume, and temperature changes between your two states. If only temperature is changing while pressure stays fixed, that's Charles' law, and the main Charles law calculator needs one fewer input to solve it. If only pressure and volume are changing at constant temperature, that's Boyle's law. If only pressure and temperature are changing at constant volume — a sealed rigid container being heated, for instance — that's Gay-Lussac's law. Using the matching single-variable calculator in any of those cases is simpler, since it asks for one less value and skips a multiplication step.

The combined gas law earns its keep once two or all three variables move together, like the weather balloon above where pressure, volume, and temperature all changed at once. What it can't handle is a change in the amount of gas itself — moles added or removed, gas leaking out, or a reaction consuming some of it. For that, step up to the Ideal Gas Law calculator, which adds the mole count n and the gas constant R into the mix via PV = nRT. Every combined-gas-law problem is really a special case of the ideal gas law where n happens to stay fixed — the same relationship Boyle's, Charles', and Gay-Lussac's laws each have to the combined law one level down.

Frequently Asked Questions About the Combined Gas Law

  • What is the combined gas law?

    The combined gas law states that P₁V₁/T₁ = P₂V₂/T₂ for a fixed mass of gas — it merges Boyle’s law, Charles’ law, and Gay-Lussac’s law into one relation so pressure, volume, and temperature can all change between the two states, not just one at a time.

  • What is the formula for the combined gas law?

    P₁V₁/T₁ = P₂V₂/T₂, where the subscript 1 marks the initial state and 2 the final state of the same gas sample. Temperature must be in an absolute scale — Kelvin — for the ratio to mean anything physically.

  • Why does temperature have to be in Kelvin?

    Because Celsius and Fahrenheit have arbitrary zero points, not a true zero. Doubling a Celsius reading doesn’t double the gas’s actual thermal energy, so plugging °C or °F straight into the ratio gives a meaningless answer. Kelvin starts at absolute zero, where the relation is derived from, so this calculator always converts to Kelvin internally before solving.

  • How is the combined gas law different from the ideal gas law?

    The combined gas law compares two states of the same fixed amount of gas and never mentions moles. The ideal gas law, PV = nRT, adds the amount of gas n and the gas constant R, so it works even when moles are added or removed, not just for a two-state comparison.

  • Can I use the combined gas law if only one variable changes?

    You can, but it collapses back to the simpler law: hold T constant and it’s Boyle’s law, hold P constant and it’s Charles’ law, hold V constant and it’s Gay-Lussac’s law. Using the single-variable calculator for that case is faster since it needs one less input.

  • What units can I use in this calculator?

    Pressure accepts kPa, atm, mmHg, or psi; volume accepts L, mL, m³, or ft³; temperature accepts K, °C, or °F. Mix and match freely between the initial and final state — each field converts to a common internal unit before the calculator solves.

  • Why do I need to enter five values instead of four?

    The combined gas law has six variables — two pressures, two volumes, two temperatures — instead of Boyle’s or Charles’ four. Knowing any five pins down the sixth uniquely, the same way three of Boyle’s four values pin down the fourth.

Need a different variable held constant, or want to convert your inputs first? These companion tools cover the rest of the gas law family.